Even if it looks like you circuit pattern is totally developed, it is quite likely that
a VERY thin layer of resist is remaining in the so called "developed areas"
preventing your etchant from attacking the copper.
a. Are you using the developing solution recommended by the manufacturer of the spray
photoresist?
Spray resists (negative and positive) tend to be very particular in their response to
developing solutions. Make sure that your is made up exactly as the manufacturer
recommends and that you use as fresh a solution as possible. Dry-film photopolymers tend
to be MUCH more forgiving of solution makeup.
b. Have you calibrated
you exposure source to insure that you are getting adequate illumination to insure
reliable image transfer?
If you are using a positive resist (contrast preserving), this is especially critical
since the UV light makes the exposed photopolymer easier to remove. If you do not have
enough light, you might not be able to develop off the areas that you intend to etch.
If you are using a negative resist (contrast reversing), the UV exposed areas might not
be sufficiently cured to resist the developing solution long enough to allow you to
totally clear the unexposed regions.
c. Can you feel a slimy coating in the developed areas after developing?
If the apparently clear copper areas have a slimy feel (much like the feel of a layer
of liquid soap), some residual resist is left on the board. Increase you developing time
or try lightly scrubbing these areas with a kitchen sponge as indicated in the Developing section if the Green CirKit
manual.
d. Are you heating your ferric chloride prior to trying to etch?
Heating to about 120F always helps to increase the activity of this material.